Workflow
Open the layer to be extended in MapInfo Pro
Display relation list
Call the relationship structure in the context menu of the relevant level.
Add field
Select a suitable name for the column in the Name field and close with OK.
End action with "Close all
Reload the edited layer in CM
Now the additional field is available and can be filled with selected data.
This configuration is done in the library under MapInfo->CM Properties<->External Programs